【主要论著】 2019-2011 代表性论文 1. Xinghao Qi, Tingting Zheng, Jinhao Zhou, Yanhong Dong, Xia Zuo, Xiaoyan Li,* Hongjian Sun,* Olaf Fuhr and Dieter Fenske, Synthesis and Catalytic Activity of Iron Hydride Ligated with Bidentate N‑Heterocyclic Silylenes for Hydroboration of Carbonyl Compounds, Organometallics, 2019, 38, 268−277. 2. Shishuai Ren, Yangyang Wang, Fei, Hongjian Sun, Xiaoyan Li,⁎, Dehydration of primary amides to nitriles catalyzed by [CNC]-pincer hydrido cobalt(III) complexes, Catal. Commun., 2019, 120, 72–75. 3. Yangyang Wang, Zheng Du*, Tingting Zheng*, Hongjian Sun, Xiaoyan Li,⁎ Efficient transfer hydrogenation of carbonyl compounds catalyzed by selenophenolato hydrido iron(II) complexes, Catal. Commun., 2019, 124, 32–35. 4. Yangyang Wang, Shishuai Ren, Wenbo Zhang, Benjing Xue, Xinghao Qi, Hongjian Sun, Xiaoyan Li,⁎ Olaf Fuhr, Dieter Fenske, Syntheses of hydrido selenophenolato iron(II) complexes and their catalytic application in hydrosilylation of aldehydes and ketones, Catal. Commun., 2018, 115, 1–5. 5. Xinghao Qi, Hongjian Sun,* Xiaoyan Li,* Olaf Fuhr and Dieter Fenske, Synthesis and catalytic activity of N-heterocyclic silylene (NHSi) cobalt hydride for Kumada coupling reactions, Dalton Trans., 2018, 47, 2581–2588. 6. Junyang Xing, Hongjian Sun, Tingting Zheng, Xinghao Qi, Xiaoyan Li,* Olaf Fuhr, Dieter Fenske, Syntheses and properties of 2-azaallyl Iron(I) complexes via Csp3-H bond activation, J. Organomet. Chem. 2018, 868, 61-65. 7. Xinghao Qi, Hua Zhao, Hongjian Sun, Xiaoyan Li,* Olaf Fuhr and Dieter Fenske, Synthesis and catalytic application of [PPP]-pincer iron, nickel and cobalt complexes for the hydrosilylation of aldehydes and ketones, New J. Chem., 2018, 42, 16583-16590. 8. Zijing Wang, Tingting Zheng, Hongjian Sun, Xiaoyan Li,* Olaf Fuhr and Dieter Fenske, Sonogashira reactions of alkyl halides catalyzed by NHC [CNN] pincer nickel(II) complexes, New J. Chem., 2018, 42, 11465-11470. 9. Fei Yang, Yangyang Wang, Faguan Lu, Shangqing Xie, Xinghao Qi, Hongjian Sun, Xiaoyan Li,* Olaf Fuhr and Dieter Fenske, Preparation of hydrido [CNC]-pincer cobalt complexes via selective C–H/C–F bond activation and their catalytic performances, New J. Chem., 2018, 42, 15578-15586. 10. Hua Zhang, Junyang Xing, Yanhong Dong, Shangqing Xie, Shishuai Ren, Xinghao Qi, Hongjian Sun, Xiaoyan Li,* Olaf Fuhr and Dieter Fenske, Phosphine-assisted C–H bond activation in Schiff bases and formation of novel organo cobalt complexes bearing Schiff base ligands, New J. Chem., 2018, 42, 4646-4652. 11. Zijing Wang, Xiaoyan Li, Hongjian Sun,* Olaf Fuhr, and Dieter Fenske, Synthesis of NHC Pincer Hydrido Nickel Complexes and Their Catalytic Applications in Hydrodehalogenation, Organometallics, 2018, 37, 539−544. 12. Peng Zhang, Xiaoyan Li, Xinghao Qi, Hongjian Sun,* Olaf Fuhr and Dieter Fenske, Transfer hydrogenation of aldehydes catalyzed by silyl hydrido iron complexes bearing a [PSiP] pincer ligand, RSC Adv., 2018, 8, 14092–14099. 13. Shishuai Ren, Shangqing Xie, Tingting Zheng, Yangyang Wang, Shilu Xu, Benjing Xue, Xiaoyan Li, Hongjian Sun,* Olaf Fuhr, and Dieter Fenske, Synthesis of silyl iron hydride via Si–H activation and its dual catalytic application in the hydrosilylation of carbonyl compounds and dehydration of benzamides†, Dalton Trans., 2018, 47, 4352–4359. 14. Yanhong Dong, Yaomin Shi, Yizheng Geng, Tingting Zheng, Xiaoyan Li, Hongjian Sun,*Olaf Fuhr, Dieter Fenske, Synthesis and characterization of bissilyl cobalt and iron hydrides bearing disilazane ligands via Si-H bond activation, Inorganica Chimica Acta, 2018, 471, ,99-103. 15. Peng Zhang, Shilu Xu, Xiaoyan Li, Xinghao Qi,Hongjian Sun,*Olaf Fuhr, Dieter Fenske, Synthesis and reactivity of silyl cobalt complexes bearing a tetradentate phosphine silyl ligand via Si-H bond activation, polyhedron, 2018, 143, 165-170. 16. Benjing Xue, Hongjian Sun, Shishuai Ren, Xiaoyan Li*, and Olaf Fuhr,Vinyl/Phenyl Exchange Reaction within Vinyl Nickel Complexes Bearing Chelate [P, S]-Ligands, Organometallics, 2017, 36, 4246-4255. 17. Hongwei Zhou, Huaxin Luan , Tingting Zheng , Xinghao Qi, Hongjian Sun, Xiaoyan Li* , Olaf Fuhr, Dieter Fenske, Synthesis and reactivity of iron hydride with [P, Se]-chelate ligand,Journal of Organometallic Chemistry, 2017, 853, 107-112. 18. Luan, Huaxin Sun, Hongjian Xue, Benjing Li, Xiaoyan*, Synthesis and Properties of a Se-Coordinated Hydrido Cobalt(III) Complex Supported by Trimethylphosphine, Chin. J. Org. Chem. 37, 2017, 1392-1397. 19. Yizheng Geng, Junyu Chen, Haiwei Zhao,Hongjian Sun, Benjing Xue,Xiaoyan Li,*Olaf Fuhr, and Dieter Fenske[,Synthesis and Structure of Low-valent η4-Cinnamaldehyde Cobalt Complexes, Z. Anorg. Allg. Chem. 643, 2017, 712–716. 20. Shilu Xu, Peng Zhang, Xing, Xiaoyan Li, Benjing Xue, Hongjian Sun,* Olaf Fuhr, and Dieter Fenske,Synthesis of Silyl Cobalt Hydride and its Catalytic Performance in Kumada Coupling Reactions, Chemistry, a Asian journal, 12, 2017, 1234-1239. 21. Junyang Xing, Hongjian Sun, Benjing Xue,† Xiaoyan Li,* Olaf Fuhr, and Dieter Fenske,Formation of 2‑Azaallyl Cobalt(I) Complexes by Csp3−H Bond Activation,Organometallics, 36, 2017, 975-980. 22. Benjing Xue , Hongjian Sun, Qingfen Niu , Xiaoyan Li *, Olaf Fuhr, Dieter Fenske,Catalytic hydrosilylation of carbonyl compounds by hydrido thiophenolato iron(II) complexes,Catalysis Communications, 94, 2017, 23-28. 23. Lin Wang, Hongjian Sun, Zhenyu Zuo, Benjing Xue,Xiaoyan Li,* Olaf Fuhr, Dieter Fenske, , Reactions of iron(II) hydrides formed by selective C-F/C-H bond activation in fluoroaryl-imines,Inorganica Chimica Acta, 461, 2017, 64-70. 24. Tingting Zheng, Junye Li, Shumiao Zhang, Benjing Xue,Hongjian Sun, Xiaoyan Li,*Olaf Fuhr and Dieter Fenske, Selective C−F and C−H Activation of Fluoroarenes by Fe(PMe3)4 and Catalytic Performance of Iron Hydride in Hydrosilylation of Carbonyl Compounds, Organometallics, 2016, 35,3538-3545. 25. Lin Wang, Hongjian Sun, Xiaoyan Li,* Olaf Fuhr, Dieter Fenske, The Selective Activation of C-F Bond with the Auxiliary of Strong Lewis Acid --- A Method to Change the Activation Preference of C-F and C-H bond, DaltonTrans., 2016, 5,18133-18141. 26. Benjing Xue, Hongjian Sun, YanWang, Tingting Zheng, Xiaoyan L*, Olaf Fuhr, Dieter Fenske, Efficient reductive dehydration of primary amides to nitriles catalyzed by hydrido thiophenolato iron(II) complexes under hydrosilation conditions, Catalysis Communications, 2016, 86, 148–150. 27. Shumiao Zhang, Xiaoyan Li, Hongjian Sun, * Olaf Fuhr, Dieter Fenske, Nickel(II) complexes of amine functionalized N-heterocyclic carbenes (NHCs), synthesis and catalysis in Kumada coupling of aryl chlorides, J. Organomet.Chem., 2016,820,41-45. 28. 仉 花 孙宏建 李晓燕*,过渡金属氢化物在CO2活化和功能化反应中的应用, 有机化学,2016, DOI: 10.6023/cjoc201605037. 29. Lin Wang, Hongjian Sun, Zhenyu Zuo, Xiaoyan Li,* ,Weiqin Xu, Robert Langer, Olaf Fuhr, Dieter Fenske , The Activation of CO2, CS2 and the Formic Acid Dehydrogenation Catalyzed by Iron(II) Hydride Complexes, Eur.J. Inorg. Chem., 2016,10.1002/ejic.201600642. 30. Yaomin Shi, Xiaoyan Li, Tingting Zheng, Benjing Xue, Shumiao Zhang, Hongjian Sun*, Olaf Fuhr, Dieter Fenske, Synthesis and Reactivity of Silyl Iron Hydride via Si-H Bond Activation, Inorganica Chimica Acta, 2016, dx.doi.org.2016.10.017. 31. Xiong, Zichang; Li, Xiaoyan; Zhang, Shumiao; Shi,Yaomin and Sun, Hongjian*, Synthesis and Reactivity of N‑Heterocyclic PSiP Pincer Iron and Cobalt Complexes and Catalytic Application of Cobalt Hydride in Kumada Coupling Reactions, Organometallics, 35, 357−363, 2016. 32. Qingfen Niu, Shumiao Zhang, Xiaoyan Li, Hongjian Sun,* Olaf Fuhr and Dieter Fenske, Synthesis and Characterization of Diorganocobalt Chlorides by Aliphatic Vinylic C–Cl Bond Activation, Z. Anorg. Allg. Chem.,2016, 642, 866-869. 33. Yuan, Shuo; Sun, Hongjian; Zhang, Shumiao; Li, Xiaoyan*, Synthesis of fluorophenyl carbonyl cobalt(I) complexes and decarbonylation of 2,4,5-trifluorobenzaldehyde catalyzed by CoMe(PMe3)4, Inorganica Chimica Acta, 43, 100–105, 2016. 34. Wang, Lin; Sun, Hongjian; Li, Xiaoyan*, Imine Nitrogen Bridged Binuclear Nickel Complexes via N−H Bond Activation: Synthesis, Characterization, Unexpected C,N-Coupling Reaction, and Their Catalytic Application in Hydrosilylation of Aldehydes, Organometallics, 34, 5175−5182, 2015. 35. Zhou, Hongwei; Sun, Hongjian; Zhang, Shumiao; Li, Xiaoyan*,Synthesis and Reactivity of a Hydrido CNC Pincer Cobalt(III) Complex and Its Application in Hydrosilylation of Aldehydes and Ketones, Organometallics, 34, 1479−1486, 2015. 36. Xue, Benjing; Sun, Hongjian; Li, Xiaoyan*, Syntheses and catalytic application of hydrido iron(II) complexes with [P,S]-chelating ligands in hydrosilylation of aldehydes and ketones, RSC Adv.,5, 52000-52006, 2015. 37. Zhang, Shumiao;, Li, Xiaoyan Li and Sun,Hongjian*, Selective amination of aryl chlorides catalysed by Ni(PMe3)4, Dalton Trans., 44, 16224-16227,2015. 38. Zhao,Hua; Sun, Hongjian; Zhang, Shumiao; Li, Xiaoyan*,Synthesis and Characterization of Iron, Cobalt, and Nickel [PNP] Pincer Amido Complexes by N–H Activation, Z. Anorg. Allg. Chem. 641, (14),2435–2439,2015. 39. 赵华,孙宏建,王麟,李晓燕*,利用碳氢键活化合成钴的钳式配合物及其性质研究, 化 学 学 报, DOI: 10.6023/A15030190,2015. 40. Peng, Zheng; Sun, Hongjian; Du, Aiqin; Li, Xiaoyan*,Introduction of (2-CF3)Phenyl Group via Nickel-catalyzed C–Cl Bond Activation and Arylation, Z. Anorg. Allg. Chem., 641, (5), 838–84, 2015. 41. Huang, Shaofeng, Zhao, Hua, Li,Xiaoyan, Wang, Lin and Sun, Hongjian,*,Synthesis of [POCOP]-pincer iron and cobalt complexes via Csp3–H activation and catalytic application of iron hydride in hydrosilylation reactions, Rsc Adv., 5, 15660-15667, 2015. 42. Zhu, Gengyu, Wang, Lin, Sun,Hongjian, Li, Xiaoyan,* Formation of PCP pincer cobalt complexes with cobalt acyclopropane moieties via double Csp 3–H bond activation, Rsc Adv., 5,19402-19408, 2015. 43. Niu,Qingfen; Zhang,Xiaohan; Zhang,Shumiao; Li, Xiaoyan and Sun, Hongjian*, Activation of vinylic carbon–chlorine bond by nickel complexes supported with phosphine ligands, Qingfen Niu, Inorg.Chim. Acta., 426, 165-170,2015. 44. Xu,Shilu, Li, Xiaoyan, Zhang Shumiao,Sun, Hongjian*, Synthesis and characterization of stable tripodal silyl ironand nickel Complexes, Inorg. Chim. Acta., 430, 161-167, 2015. 45. Guo, Yingmian, Zhang, Xiaohan,Wang, Lin, Sun, Hongjian and Li, Xiaoyan,*,Synthesis of Dinuclear Nickel Complexes from Dimethyltris(trimethylphosphine)nickel(II) via N–H Bond Activation, Z. Anorg. Allg. Chem., 641, 669-672, 2015. 46. Wang, Lin, Sun, Hongjian and Li,Xiaoyan,*Synthesis of Iron Hydrides via Selective C-F/C-H Bond Activation in Fluoroaryl-imines and their Applications in Catalytic Reduction Reactions, Eur.J. Inorg. Chem., 2732–2743, 2015. 47. Zhou, Hongwei, Sun, Hongjian,Zheng, Tingting, Zhang, Shumiao, Li, Xiaoyan*, Synthesis of Vinyl Nickel and Nickelacyclopropane Complexes Containing a Chelate [P, Se]-ligand, Eur.J.Inorg. Chem., 3139–3145, 2015. 48. Zhao,Hua, Sun, Hongjian and Li,Xiaoyan*, Synthesisand Catalytic Property of Iron Pincer Complexes Generated byCsp3-H Activation, Organometallics 33,3535-3539,2014. 49. Zuo, Zhenyu, Sun,Hongjian, Wang,Lin and Li,Xiaoyan*, Hydrosilylation of Aldehydes and Ketones Catalyzed by Hydrido Iron Complexes Bearing Imine Ligands, DaltonTrans., 43,11716-11722, 2014. 50. Zhu, Gengyu; Li, Xiaoyan; Xu, Guoqiang; Wang, Lin; Sun, Hongjian*,A new PC(sp3)P ligand and its coordination chemistry with low-valent iron,cobalt and nickel complexes, Dalton Trans., DOI:10.1039/C4DT00639A, 2014. 51. Sun, Yunqiang, Li, Xiaoyan; Sun, Hongjian*,Arylation of non-activatedC–Cl bond with Grignard reagents catalyzed by pincer [PCP]-nickel complexes, Inorg. Chim. Acta, 415, 95–97, 2014. 52. Li, Junye; Li, Xiaoyan; Wang Lin; HuQingping*; Sun, Hongjian*, Selective C-Cl Bond Activation and CatalyticHydrodechlorination of Hexachlorobenzene by Cobalt and Nickel Complexes withSodium Formate as Reducing Agent, DaltonTrans.,43,6660-6666 , 2014. 53. Lu, Yunqiang; Li, Xiaoyan; Wang, Lin; Sun,Hongjian*, C-O Bond Activation and Subsequent Decarbonylation ofEster Promoted by Fe(PMe3)4, Inorg. Chem. Comm.,41,51-53, 2014. 54. Lu, Faguan; Sun, Hongjian; Du, Aiqin; Feng, Lei;Li, Xiaoyan*, Selective Alkylation andArylation of C−F Bond with Grignard Reagents,Org.Lett., 16,772-775, 2014. 55. Sun, Yunqiang; Sun, Hongjian; Jia, Jiong;Du Aiqin; Li, Xiaoyan*, Transition-Metal-Free Synthesis of Fluorinated Arenesfrom Perfluorinated Arenes Coupled with Grignard Reagents, Organometallics, 33, 1079−1081, 2014. 56. Niu, Qingfen ; Sun, Hongjian ; Wang, Lin; Hu,Qingping* and Li, Xiaoyan*, Reactivity ofmer-hydrido(2-mercaptobenzoyl)tris(trimethylphosphine)cobalt(III) complex, Dalton Trans., 43, 4059–4066, 2014. 57. Li, Junye;Zheng, Tingting; Sun, Hongjian; Xu, Wengang; Li, Xiaoyan*, Selective C-F / C-HBond Activation of Fluoroarenes by Cobalt Complex supported withphosphine ligands, Dalton Trans., 42, 5740-5748, 2013. 58. Wu, Siquan; Li, Xiaoyan; Xiong, Zichang; Xu, Wengang; Lu, Yunqiang; andSun Hongjian*, Synthesis and Reactivity of Silyl Iron, Cobalt, and NickelComplexes Bearing a [PSiP]-Pincer Ligand via Si−H Bond Activation, Organometallics, 32, 3227-3237, 2013. 59. Huang, Ning; Li, Xiaoyan; Sun, Hongjian*, Nickel–heterocumulenecomplexes stabilized by trimethylphosphine: Synthesis, characterization andcatalytic application in organozinc coupling with CS2, Inorg. Chim. Acta, 394, 446–451, 2013. 60. Xu, Wengwng; Sun, Hongjian; Xiong, Zichang; LiXiaoyan*, Acid-Promoted SelectiveCarbon−Fluorine Bond Activation and Functionalization of Hexafluoropropene byNickel Complexes Supported with Phosphine Ligands,Organometallics, 32, 7122-7132, 2013. 61. Niu, Qingfen; Sun, Hongjian; Li,Xiaoyan*; Klein, H.-F. and Flörke,Ulrich, Synthesis and Catalytic Application in Hydrosilylation of the Complexmer-Hydrido(2-mercaptobenzoyl)tris(trimethylphosphine)cobalt(III), Organometallics, 32, 5235-5238, 2013. 62. Li, Junye; Zheng, Tingting; Sun,Hongjian; Li, Xiaoyan*, Selectivelycatalytic hydrodefluorination of perfluoroarenes by Co(PMe3)4with sodium formate as reducing agent and mechanism study,Dalton Trans., 42, 13048-13053, 2013. 63. Li, Junye; Li, Xiaoyan; Sun, Hongjian*, Synthesis and characterization ofnovel organonickel and organocobalt complexes via carbonechlorine bondactivation, J. Organomet. Chem. 743,114-122, 2013. 64. Li, Junye; Wang,Chenggen; Li, Xiaoyan and Sun, Hongjian*, C–Cl bond activation ofortho-chlorinated benzamides by nickel and cobalt compounds supported withphosphine ligands, Dalton Trans., 41,8715-8722, 2012. 65. Liu, Nazhen; Li, Xiaoyan; Xu,Xiaofeng; Wang, Zhiping; Sun, Hongjian*, Synthesis, structure and DFTstudy of dinuclear iron, cobalt and nickel complexes withcyclopentadienyl-metal moieties. DaltonTrans., 40, 6886–6892, 2011. 66. Liu, Nazhen; Li, Xiaoyan; Sun, Hongjian*, Synthesis and properties ofnovel ortho-metalated cobalt(I) andiron(II) complexes through Csp2-H bond activation of dibenzylphenylphosphine. J. Organomet. Chem.,696, 2537-2542, 2011. 67. Xu, Guoqiang; Li, Xiaoyan; Sun, Hongjian*, Nickel-catalyzedcross-coupling of primary alkyl halides with phenylethynyl- andtrimethylsilyethynyllithium reagents. J. Organomet. Chem.696, 3011-3014, 2011. 68. Zhang, Chen; Li,Xiaoyan; Sun, Hongjian*, Palladium-catalyzedhydrodechlorination of ary chlorides and its mechanism. Inorg. Chim. Acta, 365, 133-136, 2011. 69. Wang, Chenggen; Sun,Hongjian; Hu, Qingping; Li, Xiaoyan*, Carbonylativeformation of N-acetyl-2,6-difluorobenzamide through N-H bond activation of2,6-difluorobenzamide with Ni(II) complex supported with phosphine ligands. J. Organomet. Chem., 696, 2815-2819, 2011. 70. Xu, Xiaofeng; Sun,Hongjian; Shi, Yujie; Jia, Jiong and Li, Xiaoyan *,Imine-assisted C–F bond activation by electron-rich iron complexessupported by trimethylphosphine. DaltonTrans., 40, 7866–7872, 2011.
【科研项目】2013.01--2016.12 铁、钴和镍配合物对Si-H键的活化及功能化作用,国家自然科学基金(批准号:21272138)。 2011.01--2013.12 铁、钴和镍的钳式配合物在碳碳和碳杂原子偶联反应中的催化作用,国家自然科学基金(批准号:21072113)。 2009.01--2011.12 低价态铁、钴和镍有机膦配合物对C-Cl键的活化及功能化反应研究,国家自然科学基金(批准号:20872080)。 2004.01--2006.12 离子型过渡金属双亚胺配合物的合成及其在离子液体中的催化作用,国家自然科学基金(批准号:20372042)。 2011.01--2013.12 钳式配合物在碳碳偶联反应中的催化作用,山东省自然科学基金重点项目。2007.01--2008.12 环境友好的芳香族氯化物的催化脱氯研究,山东省自然科学基金。 2001.01--2005.12 环境友好的有机催化反应,山东省科技开发项目。 【科研成果】已发表学术论文160余篇 【拟招收研究生情况】每年计划招收2名硕士研究生,1-2名博士研究生。
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